I haven't read all of randy's articles but here's what goes on with calcium and alkalinity. We'll assume that alkalinity is measured solely as carbonate alkalinity, that is the CO3(-2) ion.
In a reef tank we're concerned with:
CaCO3(s) <-----> Ca(2+) + CO3(-2)
at a pH of 8.3 this reaction can only go so far to the right to give you dissolved ions. By adding Ca, by Le Chatelier's principle it will drive the reaction to the left, essentially precipitating out some of the carbonate ion in solution if you add an excess of calcium (by adding Kent liquid calcium for instance).
I would not necessarily be concerned by your alkalinity, even at 14dkh. The results of this seemingly "high" concentration are probably not detrimental. Most people are worried by high alkalinity because as a result they have a difficult time keeping their calcium where they want it (stony corals, not softies as much). This said, you needn't be overly concerned with your calcium nor your alkalinity at this point.
You can spend lots of time and $ attempting to adjust your alkalinity and Ca to the cookbook values of 7-12 and 400-450 respectively, but it may not gain you much. Liquid supplements get to be expensive really quick. Anyway, regardless... Dose as per directions if you choose to, but water changes are cheap, easy and difficult to overdose

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