If you dissolve 0.084 grams of baking soda in a liter of RO/DI water (check to make sure its alkalinity is 0), then that should have an alkalinity of 1 meq/L (2.8 dKH).
To get better sensitivity from the balance and the kit, I'd use 4 times that, or 0.34 grams baking soda in 1 L (= 4 meq/L = 11 dKH).
I would get a fresh box and not bake it. Absorbed moisture would be a problem, as would driven out CO2 and water. How much either of those may have happened in advance of your getting it is a limitation on the accuracy of the standard.
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