You really don't have a chance of doing it easily if you can't get to the rock he resides in. If you can, block up the hole that he darts into with something--netting, another rock, whatever. Spook him and he will freak as soon as he realizes he can't get to it. They will typically panic and freeze up in the nearest bolt hole they can find.
If you can reach a trigger once it locks itself into a rock, it is pretty straightforward to get them. I would use a glove in case he decides to bite, but generally they don't try to move even if you grab them hard. Once you do, you have to get their stout dorsal spine down by flicking the "trigger" behind it.
Had to do this a half dozen times for some big triggers in our reef tank that were causing problems. In some cases they dove into rock tunnels about 2 feet deep. When you get close, they grunt very loudly, sounds like a pneumatic drill underwater. See my av for photo evidence <<<
