The day of hatch they tend to turn from all silver to having kind of an almost copper look. The eyes become a lot more defined. The parents will often get a lot more frenzied about fanning the eggs on hatch day.
Clownfish are very consistent in their timing. Once you watch a few spawns and pay attention to how many days between spawn and hatch, it will be the same every time if your temperature and tank conditions stay the same.
They will typically hatch shortly after the lights go out. If you've watched your timing and are sure you've got the right hatch day, the best way to get the most larvae is to cut the pumps when lights go off, make sure there's no ambient light in the room, wait about 30 minutes to check with a flashlight to see if there are swimming larvae. If not, check back in 15 - 20 minutes.
Did you ever get and read Joyce Wilkerson's book, "Clownfish"? It tells you everything you need to do.