Live rock will work, but don't put it back in the main display. I don't think copper ruins the biomedia, but it may remain in the water (and the rock) which could leech back into the main display (hence why you shouldn't run it there.)
I don't use LR in the QT, because I sanitize everything after the QT period. I use biomedia in a mesh bag, but throw it away when I'm done. It's not that expensive and I wouldn't risk putting diseases into the main display to save $5 worth of ceramic.