Your skimmer won't have any effect on this. White vinegar is safe to use, and can be used when cleaning equipment, pumps, and even a tank if you had to start over and wanted all of the walls cleaned up like new again.
It is available at any grocery store. Just don't overdo it at this point. If you can get the pH to 8.4, that's good enough.
What caused it to rise so high in the first place? Did you dose baking soda or pH buffer?