When you purchase water you are at the mercy of whoever you buy it from. I have never seen a Wal Mart or any other water& ice type store that sells RO/DI, only RO that may or may not be treated with UV, never DI. That being said RO only is not going to have a 0 TDS so you will always have something in it albeit less than tap water. I have seen LFS that sell RO water but after testing some of them or seeing what they store the treated water in I would rather but it at the grocery store. Filtered water must be stored properly or you are no better off than if you had not filtered it.
An RO/DI is a good investment not only for your aquariums but I use it for cooking, drinking, brewing and the icemaker too.