Kalk is powdered calcium---ground up limestone, I guess. I use Mrs Wages' Pickling Lime tossed pretty cavalierly into a 32 gallon ATO reservoir: I don't measure anywhere near accurately, since only 2 tsp per gallon WILL dissolve in ro/di water, and if any falls to the bottom undissolved, a new add of ro/di will dissolve that. Kind of self-measuring in that regard. It can't RAISE your calcium on its own, but if you set your parameters to 8.3 alk, 420 calcium, and 1350 magnesium, the ATO feed will MAINTAIN all those parameters at once---except the mg, which depletes real slowly. Once the mg dips below 1200, the alk will fall, which then causes the cal to fall---so if you just test your mg once a week and add more if it's trending down---you can maintain those parameters steady as a rock for weeks on end. I've dosed up my mg a shade high and left town, with instructions only for the reefsitter to add more ro/di from a second barrel after 2 weeks, and came back after a month's absence to a perfectly-parametered reef---in fact, everything had grown nicely.