Polymethyl methacrylate (PMMA) or poly(methyl 2-methylpropenoate) is the synthetic polymer of methyl methacrylate. This thermoplastic and transparent plastic is sold by the tradenames Plexiglas, Perspex, Plazcryl,Acrylite, Acrylplast, Altuglas, and Lucite and is commonly called acrylic glass or simply acrylic. The material was developed in 1928 in various laboratories and was brought to market in 1933 by Rohm and Haas Company.
Properties
The material is often used as an alternative to glass. Differences in the properties of the two materials include:
PMMA is lighter: its density (1190 kg/m3) is about half that of glass.
PMMA does not shatter
PMMA is softer and more easily scratched than glass. This can be overcome with scratch-resistant coatings.
PMMA can be easily formed, by heating it to 100 degrees Celsius.
PMMA transmits more light (92% of visible light) than glass.
Unlike glass, PMMA does not filter UV (ultraviolet) light. PMMA transmits UV light, at best intensity, down to 300 nm. Some manufacturers coat their PMMA with UV films to add this property. On the other hand, PMMA molecules have great UV stability compared to polycarbonate.
PMMA allows infrared light of up to 2800 nm wavelength to pass. IR of longer wavelengths, up to 25,000 nm, are essentially blocked. Special formulations of colored PMMA exist to allow specific IR wavelengths to pass while blocking visible light (for remote control or heat sensor applications, for example).
PMMA can be joined using cyanoacrylate cement (so-called "Superglue"), or by using liquid di- or trichloromethane to dissolve the plastic at the joint which then fuses and sets, forming an almost invisible weld. PMMA can also be easily polished to restore cut edges to full transparency.
To produce 1 kg of PMMA, about 2 kg of petroleum is needed. In the presence of air, PMMA ignites at 460° C and burns completely to form only carbon dioxide and water.
If hydrogen atoms are substituted for the methyl groups (CH3) attached to the C atoms, poly(methyl acrylate) is produced. This soft white rubbery material is softer than PMMA because its long polymer chains are thinner and smoother and can more easily slide past each other.
PMMA Acrylic glass is commonly used for building residential and commercial grade aquariums.
PMMA is used for instance in the lenses of automobile running-lights. The spectator protection in ice hockey stadiums is made of PMMA, as are the largest windows and aquariums in the world. The material is used to produce laserdiscs, and sometimes also for DVDs, but the more expensive polycarbonate (also used for CDs) has better properties when exposed to moisture.
Chemical name poly(methyl 2-methylpropenoate)
Chemical formula (C5O2H8)n
Synonyms polymethylmethacrylate
PMMA
poly(methyl methacrylate)
methyl methacrylate resin
Molecular mass varies
CAS number 9011-14-7
Density 1.19 g/cm³
Melting point 130-140°C (265-285°F)
Boiling point 200.0 °C
Refractive index 1.492 (ë=589.3 nm)
V-number 55.3
SMILES C[C](C)C(=O)OC
Overview
Lucite® methyl methacrylate polymer was among the first plastics derived from petrochemicals. DuPont chemists discovered Lucite® in 1931 while exploring the high-pressure technology developed for ammonia production.
The polymer’s crystal-clear appearance and its strength were far superior to nitrocellulose-based plastics.
sigh.... we all are right, and yes, it is a trade name, but LUCITE is used far more often as is is made slightly different that the common "plexi-glass". Plexi glass had more "give" to it and will bow easier where as LUCITE is a bit more fragile in thin sheets.
HTH
