Do you mean topping off RODI water with increasing salinity? I don't think that's the best way to do top off since the probe can be very erroneous if left uncalibrated for just a short period of time. And also, depending on how big your tank is, the salinity might not start to increase til a very large amount of water has evaporated. But you can still do this using the programmable logic with conductiviity increasing, turn RODI pump on.
Sensors are still the best bet. If you want to incorporate the salinity probe as a fail safe then it can be done using the programmable logic conductivity alarm.