People use a pH probe because there isn't an alkalinity probe yet.
I disagree. People use a pH probe because it tells you about pH. People use alkalinity tests because it tells you about alkalinity. They are both pieces of information that are important in their own right. It's not as though pH would become unimportant if a good, inexpensive, alk probe were available. But, of the two, I'd agree that alk is more important.
With pH, the general rule is that you are looking for stability. It doesn't matter so much what the number is, but you want it to be between 7.8-8.4 or so.
With alk, you are also looking for stability, but it is more appropriate to have a "number" in mind. Different people have different opinions, but it's generally accepted that between 7-12 dKH is acceptable.
So, the two interact, but they are distinct. They generally tell you different things (e.g. alk tells you about calcifying organisms and how much stuff they are taking from the water, pH is more a reporter of the carbon dioxide level or, if you dose kalk, the rate of kalk dosing). For a reef tank, I think it's a better idea to test them separately and interpret them separately.
To be clear, do not use a pH controller to dose kalk, except to have a "high limit" as a safety measure. Always guide dosing with alk testing

. Good luck!