In low pressure aquarium use, for piping and regular fittings, there is absolutely no reason to waste money on sch 80 and you could even use thin wall pipe if you wanted, but some valving and unions can be better quality or have positive/negative size characteristics in sch 80. Sch 80 is thicker walled, but same OD pipe, so is more restrictive, and some unions and valves may have more or less restriction depending on manufacturer.