#2 is slightly overexposed in some areas, and you ended up with a little better contrast in #1. It's not about AV vs. manual, though. Neither inherently gives you better or worse pictures. Proper lighting and exposure give you the best picture. With experience, manual mode is going to give you the most control and therefore the best consistency. AV is going to let the camera do more of the thinking for you, and for a beginning photographer will end up giving you pictures that are properly exposed more consistently. You notice I didn't say "better" photos. If you pick the correct exposure in manual mode, and the camera picks the correct shutter speed to give you the correct exposure in AV, both pictures will be exactly the same. If you haven't learned to use your histogram, it can be an extremely useful tool. There are plenty of tutorials on the web, which I'm sure will do a better job of explaining than I can, but if you'd like a quick breakdown, I'd be happy to do my best at explaining it.
Now, a bit of unsolicited advice. I'd recommend shooting tank photos in RAW. This will allow you to correct your white balance in post process without affecting the quality of the picture, which can be the case when adjusting the white balance of a jpeg. Your photos could use a bit of "warming up". . .i.e. shifting the white balance slider towards the red end of the spectrum. You can also set a manual white balance, but I've found that with the lighting we use in aquarium photos, "accurate" white balance is often times not the best reproduction of what our eyes actually see.