I believe phosphates and silicates are more rate limiting for diatoms, but they do consume nitrates. Did you add anything new? I only ask, because in my experience, when pod populations drop diatoms take off, wait a few days or so and the pods start showing up again and the diatoms disappear. So if there is a new consumer, the population could have dropped. Otherwise they could have just consumed all their food sources and crashed on their own. I haven't personally found diatoms to exist if pods are around... my $.02.