Camera: Canon EOS 1Ds Mark II
Settings: RAW, ISO 200, 1/100, f/8
Lens: Tamron 28-75mm
I spend quite a bit of time in Photoshop CS3 getting everything just so-- pulling out color casts, lots of Curves adjustment layers/layer masks/brushes, etc. I really enjoy it-- far more than the shoot itslef which is always a bit nerve-racking to me.
I make basic initial adjustments in Camera Raw. Raw capture is the only way to go as far as my work has been concerned.