What is your Ca and Mg at? From another post I made, not directly relevant (no precipitation reported), but points out the importance of balancing these 3 properly to maintain desired levels:
To quote a paragraph from Randy Holmes Farley's article on Magnesium in the Reef Aquarium (see the RC Reef Chemistry Forum), "Given enough time calcium ions will interact with carbonate ions and precipitate as calcium carbonate. If you push the concentration of either too high, CaCO3 will start to precipitate. Magnesium interferes with this process, permitting both calcium and carbonate to be elevated above where they would be in the absence of magnesium". Precipitation in a nutshell!
Dave