I'm not too familiar with cement types, but check out this GARF page about making aragocrete:
http://www.garf.org/class.html
They use Riverside white cement, which I believe is type I/II (low alkalinity).
Hope that helps. I'm sure someone (uncleof6?) will chime in with regards to the type of cement. I know he has been making it for a while, so he'll be of better help than me at this point.
Edit: I was able to dig up uncleof6's recipe, which is as follows:
"Most folks get offended, when given the original DIY rock recipe, before it was spread via forums:
1 part White Portland Cement (low alkalinity type, Riverside suggested)
5 parts aragonite sand (seaflor special grade)
1 part acrylic shavings
Naturally porus (if mixed right)
Cures rapidly (pH stabilizes)
Inert, leaches nothing (no nitrates, phosphates or other "nasties") "
The thread is here:
http://www.reefcentral.com/forums/showthread.php?t=2391605