Yes, it is normal for alkalinity to drop in a reef tank, and most folks expect to add it every 1-2 days.
Baking soda is OK, although I am not a fan of independent additions of calcium and alkalinity, and much prefer to see folks use balanced additive systems, if if you make it yourself. Use of baking soda for a long period will also boost sodium relative to other cations such as magnesium (although water changes mitigate that rise a lot).
I tried using baking soda to increase my alk the day before yesterday and my skimmer went beserk. It has filled the cup 4 times now with a very light fluid. It normally uses 3-4 weeks filling the cup!
I didn't dissolve the baking soda first, just sprinkeled the powder in the sump. The brand is a local danish one, so I don't think it would help very much.
I'd try dissolving it first in fresh water, and if that doesn't help, try another brand. It is food grade baking soda, right, not something meant for other purposes?
It may have spurred bacteria or algae that themselves released products that impacted the skimmer. There may also be additional ingredients. The baking powder that I have in my kitchen also lists cornstarch that might impact a skimmer directly, or by driving bacterial growth.
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