There are calculators and such out there to help you with the how much to dose question, I went a slightly different route.
I set up my doser, to dose a smaller amount, and took measurements every day for what I was dosing...Alk, Cal, Mag, potassium. I raised the dosing each day until the levels stabilized and remained the same, then I knew I had it right. I check every now and then to make sure they are staying where I want them, and if anything changes as additions are made or corals grow.
Most don't dose Potassium, it's probably not necessary, but it's the 4th (I'm pretty sure it was 4th) largest element in NSW, so I figured keeping it where it should be can't hurt.
You definitely don't dose Phosphate.
Dosers don't have probes, you test for it with test kit's or, electronic testers like the Hanna checkers.
For the controller, pH and temp are the most popular, you'd have to decide, if you want to monitor, redox, salinty, or whatever else is available. Because pH varies throughout the day and night it's nice to monitor and see where it is throughout the day, Temp so you can use your controller to control , heaters, chillers, fans, and such.
HTH