Here's my thought on coralline: It's calcium based and calcium carbonate when solid is porous, basically all the live rock in your tank is composed mainly of calcium carbonate, dead coral, coralline etc, it's just a solid hunk of calcium which is porous when bonded in a solid form.
To answer the coralline question, no it does not impede biological filtration. If anything it it helps out the process, my rocks are almost completely covered in coralline and my tank looks the best it ever has.
I'm with agu the turkey baster is a excellent weapon of choice.