Yes, but you'll need to cure it seperately in freshwater to make sure it doesn't spike the pH. Read up on Do It Yourself Rocks, and you'll see what all the fuss is about.
I'd be worried about a cast iron block rusting in the tank and not to mention all of the oils and other fine things that are obviously embedded into the cylinder walls etc. Sounds really dangerous for the life of the fish. Cool idea though!
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