Firstly, I'd buy a copper test kit.
Secondly, stingray shouldn't really be in a reef setup around inverts. Not to mention they need a really huge tank.. the smallest being 180 to 300 gallons..
thirdly, How are you acclimating?
My calcium was 700 at one point without any loses in my shrimp only setup so thats not the issue. Are you using tap water? Some of the pipes to our plumping is metal and can release copper or heavy metals into the tap water we drink or put in our tanks. No water conditioner will take that out..
Where are you getting everything from? If everything is from the same place try buying something from another place incase your suppler is the issue here.
What type of corals? LPS and anemones will melt if they're dying.