What is Alkalinity?
Alkalinity is the sum of all the bases (compounds in water that react with acid to create neutral compounds) in the water sample. Typically, the major contributors to alkalinity are from carbonate (CO32-), bicarbonate (HCO3-), or hydroxide (OH-), and most measurements are intended to reflect the amount of these ions in solution. However, there may be contributions from other bases in the water sample, such as borates, phosphates, or silicates (this is why it’s called total alkalinity).
The amount of carbonate and bicarbonate in your water will determine how well your water is buffered against rapid changes in pH (in other words, how well your water can resist large changes in pH). Those buffer products usually use certain ratios of carbonate and bicarbonate to reach that specified pH value.
In most aquariums, the major contributions to alkalinity are due to carbonate and bicarbonate salts. As a result, your alkalinity (or total alkalinity) is dominated by carbonate and bicarbonate salts, and this is why some test kits actually call it “Carbonate Hardness,†abbreviated as “KH.†So to make some sense out of all these terms…carbonate hardness = alkalinity = total alkalinity. While this statement isn’t 100% true, it is an acceptable assumption for the average aquarist.
Now, just because carbonates and bicarbonates help your water resist changes in pH doesn’t mean that more is necessarily better. Each species of fish comes from a natural habitat with a certain amount of carbonate and bicarbonate dissolved in the water, and providing the proper amount for your fish will keep them bright, alive, and happy.
What’s the right alkalinity for my fish?
It’s a good idea to keep your alkalinity no lower than 75-100 mg CaCO3/L (equal to 75-100 ppm, 1.5-2.0 meq/L, or 4.2-5.6° dH). Below this value you run the risk of having too little buffer to accommodate small additions of acid produced by decaying waste in your tank. Most aquarium owners keep their alkalinity between 100-250 mg CaCO3/L (equal to 100-250 ppm, 2.0-5.0 meq/L, or 5.6-140° dH), depending on the needs of their inhabitants.
How do I measure alkalinity?
The most accurate way to measure alkalinity is using a titration method. A titration is a procedure in which a certain number of drops of one solution are added to your sample to produce a color change. The number of drops then corresponds to some number that represents the alkalinity. The test kits that use this method are always going to be the most accurate. Test strips will give you a basic idea of the alkalinity (or total alkalinity…or carbonate hardness) but should not be used if you require more specific values.
Hardness
What is Hardness?
Hardness or general hardness (both terms are used interchangeably) is inherently related to the alkalinity of your water. Hardness is usually considered a measure of the magnesium and calcium concentrations given in calcium carbonate (mg CaCO3/L). There’s that carbonate again!! Actually, when the hardness value is greater than the alkalinity value, then the alkalinity is considered “carbonate hardness.†The difference between the “carbonate hardness†and the “hardness†or “general hardness†value is called the “non-carbonate†hardness.