20 gallon water change in a 90 gallon tank will do nohting to the nitrate levels. It's very hard to bring nitrates down by water change as you have to do a lot consecutively for a few days. I find it easier to connect a sump filled with LR. My fish only tank has consistent 10 ppm of nitrate. It used to be around 50 ppm for a few months and it doesn't seem to affect the fish. But then, that is a fish only tank.