This setup would give a degree of surface skimming and possibly as much as an overflow. While the overflows have more lineal footage this setup would have a much greater flow in a single area so it would pull with much greater velocity.
That aside, I don't like this idea for the same reason. An overflow, by not concentrating the water movement to a small area won't pull fish, inverts, plants, etc over too easily whereas this thing will have quite a bit more force. Ever have something stuck to the intake of an in-tank power head or power filter hanging on the back? Same idea.
Why not build a simple box along the top of the back or a side? You only need a few inches of depth so it wouldn't show too much, especially if you used something like black acrylic or similar and wouldn't be a time or money consuming project.