When you first put it in, stir the heck out of it. Then let it settle for a few hours before you use it. Don't let it go in your tank right after you stir it. It won't all dissolve, there will be quite a bit of residue left. The clear water is saturated with kalk. You need to keep the pump up off the bottom of the reservoir a little so it doesn't suck in the residue. You can continue to add more water and kalk on top of the residue that is left. The residue actually helps to purify the kalk by precipitating any contaminants, so you should not only not worry about the residue, it's actually a good thing. Two or three times a year you can give the bucket a scrub and remove most of it so it doesn't build up too much.
That's really all there is to it. It's kinda hard to mess up. The only way you can really goof is to dump too much at once. Once the kalk is made up, it's pH is really really high. It can burn your skin. Most of the time the ATO only pumps in a little bit of water at once, so the effect on the tank is minimal. If you ever leave the ATO off or whatever and the level drops and you have to add more than a few mL all at once, don't use the kalk, use straight RODI for that. Topping up too much at once with kalk can shoot your pH through the roof. Most people running kalk try to have the ATO doing many many small bumps throughout the day, or even a steady drip rate that gets corrected with pure RODI.