Adding the second fixture will help the lower par areas on the edge of the light beam, but you will not doubling the par, you will be spreading out the light which will give better coverage. If this is a 3' tank, one MH bulb in the center will give you light in a cone shape from the bulb, where the light is a cone in the center, like this...
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Adding the second bulb will increase the coverage and will increase the par where the beams of light overlap, like this...
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The par at the convergent points may be doubled but the overall par in the tank will not, however you will have much better coverage which is what you want.