Hey Nanofish,
I have two Fluval SPEC's, the 2.6 gallon ones, for each of my daughters. Currently they each have one Betta in them. I do a 50% WC every two weeks and have to top off every 3-4 days with freshwater treated with Prime. I too have considered switching them both to PICO tanks. From the research I have done, (I tend to go by LiveAquaria's recommendation on minimum tank size), No fish, other than a betta, fresh or saltwater, is recommended in anything under 10g. Now, I have read people successfully keeping one single Goby in a tank under 10g, but you'll more issues with water parameters than with a fishless set-up. Softies and some LPS are typically not very hard to keep and are somewhat forgiving in regards to water parameters if provided correct lighting and temp. I do agree though that a clown would be a bad idea in anything under 20-30g for long-term health of the fish. The picture of zchauvin's tank is exactly what I am picturing for them since they are bored with their beta's. I am not sure what is best for filtration in a fishless set-up or whether to use a heater. My experience with these using freshwater, I definitely would set-up an ATO. Evaporation is crazy in ours! Good luck man and keep us updated. I'm not going to even try to set-this up until I have my RODI system hooked up.