All,
My understanding is that if you want hydrogen peroxide to supply an aquarium with oxygen, you need to run it over a catalyst (I'm not positive, but I think platinum can be used). Aquarium Pharmaceuticals had a product that did that. Otherwise, adding H2O2 is just going to oxidize other compounds, and not release much free O2.
I recently did some qualitative testing exposing H2O2 on static water samples to see what benefits might result - I was not impressed, it worked a lot like chlorine bleach<grin>. I never even bothered running quantatative tests.
Here is an exceprt from my "Advanced Marine Aquarium Techniques" book:
Hydrogen peroxide:: With the chemical formula H2O2 this compound has some unexplored uses in marine aquariums. Hydrogen peroxide is available over the counter in pharmacies as a 3.5% solution. At this level, it is not reactive enough for most potential uses. Available through some home water treatment services, a 7% concentration solution of hydrogen peroxide is stronger and has more uses. Do not use this product until you have read and fully understand the MSDS for it. Although stronger concentration of H2O2 are available, they are very reactive and their use entails too much risk. In addition, these products have had stabilizers added to them which may not be suitable for use in and around aquariums. Perhaps the most immediate use for hydrogen peroxide is as a disinfectant / oxidizer. Filter elements and other aquarium items that have been fouled with organic materials can be soaked for 24 hours in a 7% solution of hydrogen peroxide. It is much easier to rinse off than bleach is, and does not leave a toxic residue like some other disinfectants might. Knowing the propensity for this compound to give off an oxygen atom in oxidizing reactions, some people have experimented with using it to raise the ORP level of aquariums, or to temporarily enhance the dissolved oxygen level in water. Remember, like ozone, too much hydrogen peroxide can pose a threat to the animals themselves. Some researchers have shown that protozoans can be killed by doses of hydrogen peroxide ranging from 12.5 to 25ppm. Because this is in the range that some fish have shown sensitivity, more study is required.
Testing for this compound can be done using a standard DPD chlorine test, at least in terms of presence or absence.
Jay Hemdal