I'm curious as to why you would doubt it?
I had a Chiton come into one of my first tanks, most likely from live rock. It did not look quite like this one, but it also buried into the sand at night.
I have also unpacked live rock, and the bottom of the box was littered with deceased Chitons.
Whether or not one makes it's way into a tank, has a lot to do with how well the live rock has been handled during transport, and how long removed from the ocean it is.