One of the poorer “Help Me†replies I see is when someone asks, “I have a wet/dry and use bioballs. Should I replace the bioballs as I have high nitrates?†The “helper†then tells the person they should replace the bioballs with live rock rubble (small broken up pieces of LR). The bad part is, that doesn’t fix a thing and even may worsen the problem.
Remember when we talked about denitrification, we said that anoxic conditions must be present. In fully submerged live rock, located in the display or sump, the pore structure does provide a limited area for anoxic conditions to form. Now place that same rock in air and just splash oxygenated water over it hour after hour. Anoxic conditions my eye; there is not a low oxygen zone on the rock. Using rubble to replace synthetic media in a wet/dry doesn’t solve a nitrate problem. It may, in fact, make it worse as often cyanobacter will grow on the rubble. Cyano has the ability to “fix†nitrogen, that is, convert nitrogen gas to ammonia or directly to nitrate. With cyano getting all the nitrogen gas it can use with atmospheric exposure, it may well add nitrates into the tank on top of what the tank produces itself.