PH for RODI water does not matter...because it has a very low alkalinity.
In simple terms, since the water is so pure any amount of acid (such as a single drop of saliva from your mouth) would have a huge effect on the PH of the water since it has no other elements in it to balance the ions. Thus this water would have a very high PH but a very low alkalinity.
So for example, if a gallon of pure water has a pH of 1.0 (extremely acidic) and it is added to a gallon of water that has lots of free ions, (higher alkalinity) and a pH of 7 (tap water). The result would be 2 gallons with a PH of 7.0. Alkalinity is the measurement that is critical