Is the live rock cured or uncured? How big of a tank?
You will need test kits to test for ammonia and nitrite. Ammonia will gradually increase to a peak then will decline, then nitrite will increase to a peak then will decline. You want both ammonia and nitrite to be 0 ppm. At which point you can add some hardy fish to get started. This whole process would take between 30 and 90 days depending on tank conditions.
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