No buffers.
If you get to where you need more alk and ca in the water (based on your test results) kalk in the topoff is an easy and stable way to get it in.
I agree with the others No supplements to top off water, just plain RODI. You won't need to dose anything unless you get corals and then mostly it will be LPS and SPS that will need dosing. Leathers and other soft corals don't use much of anything. Your salt mix has everything you need already in it.
You really should just add rodi. Kalkwasser should only be added if something in your system is depleting your calcium and alkalinity like growing hard corals. Even if that is happening, you need to adjust the apconcentration based on the system's uptake.
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