If you are doing hypo then the fish will not take up much vitamin through the water via skin, gills, or drinking as directed by the fish's osmotic gradient. Also, B vitamins are quickly degraded in water and by light. I do not think that adding a vitamin pill will hurt your fish, but I am doubtful it will help them either.
Garlic is a potent appetite stimulant for most fish as is live food. You can also buy vitamin supplements to enrich the food which would be a more potent means of delivering the supplements.
Good luck with your hypo!