You use the same vial and sample for both the calibrate/control sample and the test sample w/ reagent? If not, I would not trust, if so, I would.
They give you two vials and a common mistake is using one for the first read and then the second w/ reagent for the second read. The test is all about measuring the refraction of light in the sample before the reagent is added--the control--to that after the reagent is added.
Using different vials/samples for these two steps introduces variability into the equation from vial imperfections and differences in the samples themselves. Best technique is to wear gloves, rinse the vial w/ tank water first, then add the tank sample (and measure w/ a pipette or something similar--NOT the line on the vial). Wipe the vial w/ a lint free cloth and ensure no air bubbles. Place vial in reader when instructed w/ the "10ml" facing forward. When instructed, remove vial, add the reagent, and gently invert 5-6 times to mix. Then wipe w/ lint free cloth again, check for air bubbles, and put back into reader w/ the "10ml" facing forward (this allows you to standardize the glass thickness).
Following this method I would trust over Salifert. I have always had trouble detecting the color change on their alk test which is why I switched. Other tests are fine (Ca and Mg).
Also, my tank runs about 7.6 and it is doing great. You could have had great success w/ an alk of 7.2 if it was stable. If I remember right, my alk was lower than what the Salifert was telling me too but I'd have to dig back through my logs to verify.