I would recommend not adding live rock that early, for reasons of cleanliness as well as stress. I siphon any detritus out of grow out tanks daily, if not twice daily; typically rocks and such get in the way and moving them out of the way to siphon stresses out the livestock. To account for the detritus lost to the depths of the live rock, more water changes would need to be done.
When is the best time? In my experience it's fine to add rock after the juveniles have been settled for at least a few weeks. Settlement is very hard on most larvae, so sufficient time should be allotted for growth to allow them to handle changes to their environment.