I've lay down bottom, then back then 2 sides then front.
silicone will take 24 - 48 hrs to cure. The glass must be cut very straight else the silicone joint will be weak in some areas. I bought the glass pre-cut from a glass shop.
Once you're done remember to fill it up and let it sit for a day or two with your equipment in it running. If you have a leak, it's gonna be a pita.
IMO, it's easier to buy a tank unless you need a specific shape. Costs about the same minus the work and wait and the second guessing if it'll hold up or not.