I used a mixure of rock rubble and Great Stuff Foam. The foam is 100% safe for marine environemnts -- it is the same stuff as waterfall foam in a different color -- but it breaks down under UV so it needs to be painted with a marine safe epoxy. The only source of this epoxy that I am aware of is Sweetwater marine epoxy from... umm... cant think of the company right now.
It does not decay (unless exposed to UV). It has been used a lot in FW tanks.
There is a very long thread on various folks using this -- try a search for "Faux Rock wall"
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