the overflow (single or double) works based on the equalization of water, assuming there is no air in the pvc pipes, then if you look inside the overflow pipe in the tank, you will see where the lowest part of the cross fitting is. if it is near the top of the overflow pipe, then you have the cross placed too high. it would need to be reduced. equalization of water is slower with smaller size pipe due to small amounts of pressure pushing the water from the overflow pipe. thats why if the cross is lower, then there can be several inches of water pressure pushing the water in the lowest part of the cross so that it can overflow, thereby allowing for greater gph activity.
if i think of a better discription, i'll post it for you if you still dont get how the overflow works. also, clamp the air value tubing so that no air can enter, those things do fair.
FWIW, i dont put air values on my overflow, i push water pipes from the JT fitting, in through the pipe and use a cheap pump to extract the air.