I'd echo the suggestion to look into Herbie and Bean Animal drains. IMHO, an emergency drain is absolutely mandatory, and a siphon drain is silent.
I'd also look into a booster pump for the RO/DI system, along with an auto-shutoff float valve for whatever container you are using to collect the RO/DI water. Every single major water spill incident I've ever had has been from leaving the RO/DI on without checking on it. I finally learned my lesson, and moved the whole thing down into the basement and put an auto-shutoff float valve on the rubbermaid brute barrel I started using to collect it.
Also, I'd suggest looking into Tropic Eden sand. IME, it runs rings around Carib-Sea. I used a fine grade carib-sea sand when I first set up my tank, and after a couple months of dust-storms, I removed most of it and replaced it with Tropic Eden mini-flakes.
If you're feeling adventurous, and you don't care about sand dwelling critters like conches, it also mich be worth considering a false sand bed made out of sand and epoxy. I kinda wish I had gone this way in my 120, it would have made high flow w/o sandstorms and keeping detritus in suspension much easier. If I ever feel REALLY adventurous, I might do it myself some day, I just picture getting a false substrate into the tank without draining it being a huge PITA.
I'd also consider ditching the foam in the sump, it will most likely end up being nothing more than a detritus trap. IME, it's much easier to just vacuum detritus off of the bottom of the sump.
Also, what are you doing to get adsorbed PO4 out of the dry rock before using it? Acid bath? Another thing you could consider would be setting up a rubbermaid bin with a cheapo koralia PH or two, and a low output pump pushing bin water through a 1-5 micron filter sock, and running an LaCl drip into it. Easier to do it now than to deal with high phosphate in the tank down the road.
Good setup! It looks like you're spending money on good stuff from the get go. It might be worth picking up Hanna Alk and Phosphate/phosphorus checkers. The Hanna alk checker is a MUCH faster way to test alk than any chemical test, and just as reliable.