When a white film appears, they are bacteria, if green, are algae. Normally a thin film the first few days, are unicellular algae, phytoplankton.
Now, most of the products you use, are to add or increase the amount of bacteria. Which is fine, but in my opinion, and it is just my opinion, not necessary.
The bacteria are already in the aquarium, and its amount will be conditioned by the space you have to live (water, rock and other items) and food. If changes in food are prograsivos, they increase or decrease in number, until something the limit (space, food ..).
So I imagine that will add bacteria and food for these, each time you do it will grow. The good news is that although only the dirty windows, also are in the water and feed on corals appreciate them. The downside is spending money, food bacteria are usually carbon sources (acid, ethanol ...).
And it depends on what you choose, if you follow a method Strictly and achieve results that we like, or try something more natural and get other results that we like.
In short, if bacteria and food for these are added, one way or another, we get dirty glasses.