I'm afraid that's not accurate. Opening windows affects the amount of CO2 in the air and that in turn affects the PH. The alkalinity also affects the PH, but the PH does not affect the alkalinity so there is no correlation between opening the windows and alkalinity.
You need to read up on alkalinity, calcium, and magnesium with how the affect reef tanks. You need to know what levels you want them at and how to test them. Then you also what to have online calculators available to you so you can find them for when you need to dose so you know how much to add and how much to spread it out. Once you have these down you will be familiar with the basics and then you can be considered a beginner. Right now you are just getting started.