Pittsburgh
New member
Could you provide some sources for this? I've seen a study or two that showed iron oxide hydroxide to release bound phosphates when the phosphate levels in the water column dropped suggesting the sequestering isn't permanent, much like phosphates bound to live rock.
From this article by Randy Holmes-Farley
He found it from this study:
3. Phosphorus phases in the surface sediment of the South Sea. Son, Jaekyung; Lee, Tongsup; Yang, Han Soeb. Dep. Marine Science, Pusan National Univ., Pusan, S. Korea. Han'guk Susan Hakhoechi (1999), 32(5), 680-687.
Some time in the past I thought I had read another one that confirmed this but my google-fu isn't working for me this morning.
Yeah, I remember reading his article as well. Too bad I can't confirm the source as the original paper (3) is in Korean. I'll try to dig up other studies I found in the past over the weekend. AFAIR, the deal is that while the bond is indeed not permanent, with GFO it is still strong and holds for many many months. In other words, unless you keep the same batch of GFO on line for a year or longer, you won't see any noticeable leaching of any kind. And even when it starts breaking, the release happens in small fractions. When I did my tests (and I had a lot of phosphates originally) the output of the GFO reactor, 2-3 weeks after the media was completely exhausted, measured no higher than phosphates level in the tank water. I was doing daily tests with hanna checker, fwiw. My tests are all subjective of course as one may argue that phosphates in water were due to released phosphates from GFO reactor. I would expect them to be higher coming out of the reactor if GFO were leaching phosphates back at any reasonable rate. The accuracy of my hanna checker is also questionable, of course.