Aside from the risk of turning your reef into a freshwater system (it happened to a local on a 200g plus system), the other issue with plumbing directly to your RODI is TDS Creep.
The RODI pressure switches require a consistent pressure to stay closed.
As water evaporates the pressure is released in small amounts over an extended period of time.
This is sub-optimal for two reasons:
1. You waste a lot more water as the waste water lines runs for a minute or two each time the valve opens. Even if it only lets a little bit into the tank.
2. As the RODI unit cycles on and off, a little bit of TDS is allowed to pass through the membrane. This will either be handled by your DI resin (shortening the lifespan) or if depleted, pass through into your tank.
I remember Russ from BFS saying the best thing to do is to produce as much water at one time as possible to minimize the effects of TDS Creep.
This is why I use a timer to fill my 5g bucket. It ensures the RODI only runs for as long as it needs to keep my Storage container full.
If you are going to use the float switch, I would add a float valve similar to the one Larry linked on the end of the line (in the sump). This will act as a failsafe should something cause the float switch to stick in the On position. I have heard of those float switches getting stuck from coraline algae growth as well as small snails.
Happy Holidays
Ken