I had a similar set up a few decades ago and I had pH problems - the pH would lower greatly. Two tanks connected at the same level allowed too much CO2 to accumulate, and the water became acidic. Air infusion did not work.
I would not simply allow water to flow into the other tank, I would use a powerful little pump, a spray bar, and a small skimmer to increase O2 levels.
And you need to monitor pH.