You shouldn't place them too close, they will compete with each other and one will eventually loose. Murphy's law rules my life and it is usually that favorite SPS that looses to that "brown frag with potential". Research your coral and place them based on their growth form (branching, tabling..etc.), lighting and flow requirements. Eventually these corals will fill out your reef and you will be amazed at how fast this will happen. Just check out the many threads on tank progression photos.
I have seen that similar types of corals will encrust on another without killing the other but this competition has to stess one or both colonies. When you have different types is where the real chemical warfare comes into play. There will be a winner and a loser.
When you get to the point of encroaching is where the fun part start, fragging! In my experience its best to place these corals apart and allow them to mature and be strong. They will handle the competition much better when they are larger. Then you can prune the corals by fragging if they start to touch and control things a bit.