carbonate-bicarbonate ratio

cmoresps

New member
Just a quick question, and maybe I am reading too much into it but here it goes. I had supersaturated carbonates ultimately caused by GFO. I no longer use GFO (leason learnt!). I have been trying to permanently liberate my system from saturation (by saturation I mean not being able to exceed alk 8dkh and ca 400). For obvious reasons, I want to get alk to 11dkh, ca 420-450. I have been using baked baking soda to raise alk in conjunction with a ca reactor I run every other day. I use a 6:1 ratio of baked baking soda to non-baked because I like the higher ph effect.

Question is: I have noticed that as time progresses, the saturation point of the water column seemingly gets lower (meaning 3 days ago I had alk 9dkh ca 440), now I can only achieve 8 dkh ca 400. I read one of Randy's articles on Calcium and it really got me wondering in that a water column's carbonate/ bicarbonate ratio effects the water column's overall point of supersaturation, when bicarbonate shifts to carbonate, it lowers the supersaturation point. In sum, by adding a mostly carbonate mix here, is that what is causing the point of supersaturation to become lower?
 
For obvious reasons, I want to get alk to 11dkh, ca 420-450

There are zero reasons to have those that high :) You missed in your post that pH is also a controlling factor in those saturation rates.

column's carbonate/ bicarbonate ratio

This ratio is ONLY controlled by pH. As the pH goes up the bicarbanate ratio shits to more carbonate and less bicarbonate. And if you increase the Alk and the pH remains the same, there will be just more of them but the ratio will be the same.

Did you see this article by Randy that get into this ?

Scroll down to where is shows


Ω = 1 (risky: dissolution of aragonite begins here)

Calcium and Alkalinity Balance Issues
http://www.reefkeeping.com/issues/2002-04/rhf/feature/index.php
 
<a href=showthread.php?s=&postid=12802800#post12802800 target=_blank>Originally posted</a> by jansenwrasse
Hey boomer you gots a spelling error on there ... it is pretty funny to read! I think he means shiFts

The is the most impressive thing I have seen in awhile. Boomer beat the computer---it never got a *** censor:D

I used the word pussycat in a post referring to a childs pet in a picture even and it even got censored.

:eek2: somethings gone wrong with the force field--it did not censor it this time.

I don't have the guts to try George Carlins7 dirty words you shouldn't say on here:lol:
 
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I think he means shiFts

:rollface: :rollface: :rollface: :rollface:

That is funny Jansen. Usually that word comes out *****
 
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