I think that it really does not matter in terms of maintaining a low residual of waste.
The reasoning is:
At 24/7 lighting, the export rate is less than the 12/12 lighting, but not a great deal less, still, the less export rate means a more stable nutrient level, so in that respect, you could argue a stable NO3/NH4 level might be better.
But on the other hand, many low nutrient reef algae like NH4 and the nighttime on cycling with a 12/12 split might provide some NH4 to the zooxanthellae, vs NO3. DBS's will also compete for NO3 and skimmers etc.
Generally speaking, I think most of the issues are resolved with 12/12 splits with the refgue being on at night. This keeps heat and electric cost down and the bulbs life down(hence cost) also.
But if the refuge is on during the day, heat and perhaps a little (insignificant??) competition for NH4 between the macros and the reef algae for NH4, which is many times more suitable for algal growth than NO3, you need 8 electrons to convert the NO3 into NH4 which is the form used by all plants.
The issue with NH4:
It's used as fast as it's produced in most planted tanks. So isotopic enrichment and labeling is about the only method that can trace it's path through a system, not a hobby level experiment
No test kit I know of is able to measure the low levels of NH4. One a rare day you might be able to measure some with a Lamott low level kit etc.
NH4 is constantly being produced by all the critters but it's used as fast as it's produced ideally.
It is in my tanks, they never have any NO3, so I add KNO3 to my tanks to supplement this. I could use NH4, but it is a very good nutrient for inducing algae blooms unlike the NO3 and NH4 is a bit like playing with fire.
I've used it extensively, best to get all the NH4/urea from critter waste.
That is why adding too many fish causes an algal bloom in a tank, not PO4, NO3, Fe etc.
PO4 might cause some, but in FW it clearly does not. I am still not convinced or am totally clear about PO4 in a SW macro plant tank, I've had diatom blooms when I've added it in the past. Still, I need to make sure it's not something else and I'm not ready yet to make a generalization there.
NO3, yes, it can be added and will help a NO3 limited tank grow better.
Then other good thing about having enough NO3 and NH4, your PO4 levels will also drop faster.
So the algal issues are different if I were to guess in a FW vs SW plant tank, but how much I'm not sure yet.
Regards,
Tom Barr