I JUST converted some mollies the other day (and have two more acclimating right now) and have done a ton of reading on it.
I can't tell you too much about guppies, but what I read in passing says you have to convert them much more slowly.
There is absolutely no consensus about mollies. Some people drop them straight in and don't lose any. Some acclimate in a separate tank over a period of weeks and still lose them (but less than if they dumped them straight in).
I got 5 mollies (lyretails, dalmations, and a panda) from PetSmart. I drip acclimated them to 1.025 over a 4 hour period. One of the 4 females gave birth during acclimation; I put a few of the babies in my display (they were immediately eaten), some in my sump refugium, and some in my display refugium.
The male died the day after being released in the display fuge but I suspect a powerhead accident. The female who gave birth didn't look well, but seems to be recovering now. Another who was pregnant dropped some or all of her babies prematurely yesterday but seems fine now. All four are eating and adjusting (I think the intense light and higher flow are more stressful for them than the transition to salt). The babies all seem to be alive as well and my poor red scooter dragonet is exhausted from trying to catch them since they are too fast for him.
I bought two more mollies yesterday and have been drip acclimating them since, but more slowly this time. They were brought up to about 1.015 in 10 hours, then I turned the drip off overnight and started it up again this morning. Both are eating and active and seem to be doing fine.
So that's my experience so far... do lots of reading and decide which way to go. There doesn't seem to be one definitive method.
Edit: You know, now that I think about it if you are converting the entire tank to salt, I'd just start topping off the evaporation with saltwater until you get to 1.025 and then switch to topping off with fresh. It will take a while, but eventually it will be where you want it and be a pretty gentle transition.
